The tuning is standard tuning.
"Come Undone" begins with a signature heavy effects laden guitar riff that is instantly recognizable. You can achieve a similar guitar tone by using a nice clean guitar tone with a heavy phaser effect, some delay and a little bit of reverb.
This opening riff requires a bit of a stretch but other than that, is pretty easy to play. That riff is used during the intro, verse and chorus sections of the song.
The pre-chorus section is the only other part we need to learn. It is a bit harder to hear within the mix, but it contains some cool arpeggiated guitar work that leads really nicely back into the main riff.
I hope you guys enjoy learning this Duran Duran classic!
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